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Stereoselective Synthesis of Chalcogen-Tethered γ-Lactams via 5-Exo-dig Cyclisation Under Visible-Light Irradiation
We report a rapid, eco-friendly, and catalyst-free method for the stereoselective synthesis of chalcogen-tethered γ-lactam...
Four-electron Oxidation and One-electron Reduction of the Bis(terphenylthiolate) U(II) Complex, U(SAriPr6)2 [AriPr6 = C6H3-2,6-(C6H2-2,4,6-iPr3)2]
The utility of the sterically bulky terphenylthiolate ligand, (SAriPr6)1- in expanding uranium reductive chemistry has bee...
Facile Synthesis of Bicyclic Heat-Resistant Energetic Materials via A C-N Coupling Strategy
Heat-resistant energetic materials are critical for applications in extreme environments, such as aerospace vehicles and t...
Surface wettability engineering of MoS2 quantum dots-decorated NiCo2O4 nanospheres for enhanced oxygen evolution reaction
Modulating MoS2 quantum dots enhances the hydrophilicity of NiCo2O4, accelerates bubble detachment, promotes mass transfer...
Comparing electrocatalytic and chemical oxygen reduction reactions by a molecular copper complex
Inspired by the CuB site in cytochrome c oxidase, a molecular CuII complex (1) featuring a mixed pyridine-phenol ligand ha...
Expanding the conjugated benzene rings of phenothiazine phosphonic acid for efficient tin-lead mixed perovskite solar cells with Sn/Pb ratio of 0.4:0.6
Interfacial defect states, redox reactions and energy level mismatch limit the progress of promising bandgap tunable tin-l...
Covalent organic frameworks membranes for rechargeable electrochemical energy storage devices: chemistry, fabrication, and future opportunities
Covalent organic frameworks (COFs) represent a class of crystalline, periodic, and porous polymeric materials constructed ...
NiMoO4 decorated Co(OH)2 nanosheets as an efficient bifunctional electrocatalyst for urea-assisted water splitting
This study puts forward a new bifunctional three-dimensional hierarchical heterostructure electrocatalyst of Co(OH)2/NiMoO...
Alkylaluminium-Catalyzed Regioselective Hydrophosphinylation of α,β-Unsaturated Ketones into γ‑Ketophosphine Oxides
A green method for regioselective hydrophosphinylation of α,β-unsaturated ketones using alkylaluminium compounds has been ...
Cross-linking teichoic acids by click chemistry prevents bacterial cell growth
This work identifies a novel antibacterial mechanism that targets the cell wall of the human pathogen Streptococcus pneumo...
Self-assembly under continuous flow conditions
Self-assembly plays a crucial role in the formation of hierarchical supramolecular structures and functional materials. Th...
Biomimetic Fluoride-Coated Zinc Anodes: Pediatric Dentistry Inspires Stable Zinc Batteries
Zn anodes face dendrite, hydrogen evolution reactions, and corrosion issues. Inspired by the pediatric dental practice of ...
Divergent [3+2] Annulations of Oxime Acetates with Thioaurones/ Aurones Leading to Benzothiazino-/Benzoyl-Pyrroles
Herein, we report the development of unprecedented copper-catalyzed intramolecular annulations of oxime acetates with thio...
Redefine the capacity limitation of Li-air battery by uncoupling the competitive multiple-transport and nucleation
An ordered thick porous air electrode was designed to decouple the O2/Li+/electron transport, redefining the relationship ...
Enantioselective palladium photoredox catalysis
The merger of visible light with transition metal catalysis, particularly palladium catalysis, has unlocked new opportunit...
Visible-Light-Induced Radical 1,3-Hydrosulfonylation of Allylketones with Sulfonyl Chlorides
A radical 1,3-hydrosulfonylation of allylketones with sulfonyl chlorides via 1,2-carbonyl migration has been achieved unde...
Iron-Catalyzed Iodonium Ion Promoted Activation of Conventional Thioglycosides for Stereoselective 1,2-Cis Furanosylations
Iron-catalyzed activation of conventional thioglycosides using iodonium ion enabled the selective synthesis of 1,2-cis fur...
Bimetallic FeSe2/CoSe2 Heterojunction Nanoparticles Anchored on Porous N-Doped Carbon Nanosheets for High-Rate Sodium-Ion Storage
Metal selenides-based anode show promise but face challenges like poor conductivity, structural devastation, and slow ion ...
Challenges and Innovations of Bipolar Membranes to Enhance Water Electrolysis Performance
Bipolar membranes (BPMs), a specialized category of ion-exchange membranes, consist of a cation-exchange layer (CEL) and a...
Historical account of dinitrogen-bridged diiron complex synthesis using a commercial tripodal ligand
The KC8 reduction of (Triphos)FeCl2 in toluene under 3.4 atm of N2 afforded [(Triphos)Fe]2(μ-N2), which features a modestl...
A nitrogen-rich graphdiyne containing hexaazatrinaphthylene for high-performance lithium-ion batteries
A nitrogen-rich graphdiyne (HATN-GDY) material containing electrochemical active hexaazatrinaphthylene units was successfu...
Synthesis of highly substituted 1,3-dienes through halonium promoted 1,2-sulfur migration of propargylic thioethers.
Conjugated 1-bromo or 1-iodo-1,3-dienes bearing a sulfide substituent have been synthesized via 1,2-sulfur migration from ...
Electrochemical detection of glutathione based on accelerated CRISPR/Cas12a trans-cleavage with MnO2 nanosheets
CRISPR/Cas12a system is accelerated by glutathione-mediated reduction of MnO2 nanosheets. By monitoring trans-cleavage eve...
Emerging Pt-based intermetallic nanoparticles for oxygen reduction reaction
The advancement of highly efficient and enduring platinum (Pt)-based electrocatalysts for the oxygen reduction reaction (O...
Sulphur-induced structural rearrangement in the self-sensitization photo-oxidation behaviour of phenothiazine-imidazole molecules
A green photo-oxidation reaction was discovered in which the imidazole ring is oxidized and rearranged to generate imidazo...
DMF as amine source: iron-catalyzed cyclization of 2H-azirines to imidazoles
A novel method has been developed for the synthesis of 1-methyl-4,5-diaryl-1H-imidazoles through Fe(II)-catalyzed cyclizat...
Iron content in aerosol particles and its impact on atmospheric chemistry
Atmospheric aerosol effects on ecological and human health remain uncertain due to their highly complex and evolving natur...
Layer-by-layer designer nanoarchitectonics for physical and chemical communications in functional materials
Nanoarchitectonics, as a post-nanotechnology concept, constructs functional materials and structures using nanounits of at...
Controllable fabrication of well-shaped PMBA@CsPbBr3 nanoparticles for highly sensitive HCl and HBr detection
We report a facile two-step strategy to construct well-shaped PMBA@CsPbBr3 nanoparticles by combining in-situ adsorption a...
Structure Prediction from Spectra amidst Dynamical Heterogeneity in Melanin
Melanin is a biopolymer pigment that plays a central role in skin photoprotection. Its extensive chemical and dynamical he...
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