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Radical Reactivity of Aryl Thianthrenium Salts
Functionalization of the C(sp2)–H bond is a challenging yet highly useful synthetic task due to its relative inertness and...
I2/DMSO-Enabled Cascade Michael Addition/Oxidative Cyclization: Access to Imidazo[2,1-b][1,3,4]thiadiazoles
A straightforward protocol for accessing imidazo[2,1-b][1,3,4]thiadiazoles via I2-catalyzed tandem Michael addition-oxidat...
Theoretical Insights into the Cu-Catalyzed Boronation of Conjugated Trienes: Mechanism and Selectivity Control
The copper-catalyzed boronation of conjugated trienes offers a promising route to organoboron compounds but is often limit...
Tandem indium(III)-catalyzed cyclization and intermolecular hydrofunctionalization of 1,6-enynes
A tandem indium(III)-catalyzed cyclization and intermolecular hydrofunctionalization of 1,6-enynes for the stereoselective...
Preparation and Catalytic Properties of Benziodolium Salts
Dibenziodolium salts have recently emerged as useful iodine (III)-type halogen bonding (XB) donors. However, although benz...
Asymmetric Transfer Hydrogenation of Polyoxygenated 3-Arylidenechroman-4-ones: A Powerful Tool for the Total Synthesis of Natural Homoisoflavonoids
A mild and highly efficient one-pot asymmetric transfer hydrogenation (ATH) of challenging, electron-rich 3arylidenechroma...
Isoquinoline-Catalyzed Visible-Light-Mediated 1,2-/1,4-Thiosulfonylation Difunctionalization Reaction of Thiosulfates with Alkenes
We have developed a novel method for the 1,2-/1,4thiosulfonylation bifunctional reaction of thiosulfates with nonaromatic ...
Dehydrogenative Aromatization of Cyclohexanone Derivatives for the Synthesis of Site-selective Substituted Phenols and Anilines
Aromatic compounds containing phenol or aniline functionalities are ubiquitous building blocks in various fields both in a...
A Versatile and Practical One-Pot Strategy for a Greener, Waste-Minimized Synthesis of Aryloxy- and Alkyloxy-Substituted Metallophthalocyanines via Tandem SNAr-cyclotetramerization
Phthalocyanines represent molecules of considerable scientific interest, yet their synthesis remains challenging, particul...
Theoretical Insight: Dual Roles of Electron-Pair Donors and Acceptors in Activating and Mediating Iodine Atom Transfer
Lewis bases (Lbs) act as electron-pair donors and react with BH3 to form Lbs→BH3 complexes. In catalytic systems, these pr...
Visible light-driven construction of isoxazoline/isoxazole scaffolds via [2+2+1] cyclization of alkenes with tert-butyl nitrite
A visible light-driven [2+2+1] cyclization of alkenes with tert-butyl nitrite (TBN) has been developed for the efficient c...
Multi-site thiolation enables rapid and precise synthesis of 2-pyridone thioethers
The direct and selective functionalization of 2-pyridones remains a fundamental challenge in synthetic chemistry. While co...
Brønsted acid-catalyzed synthesis of trifluoromethylated azulenes via cyclization of 1-phenyl-2-CF3-1,3-enynes
Azulene and its derivatives are important scaffolds with broad applications. The introduction of a trifluoromethyl group i...
Photoredox Catalyzed Visible Light-Induced Reduction of Nitroarenes into Anilines
A photochemical methodology was developed for the reduction of nitroarenes, utilizing γ-terpinene as the reductant and 9-H...
Ligand-controlled Copper-catalyzed Carboamination Reactions of Styrenes and 1,3-Enynes to Access Diverse Imides
The multi-component reaction among alkenes, nitriles and carboxylic acids via the radical Ritter-type process is one of th...
Photoinduced Iridium-Cobaloxime mediated Alkene C(sp2)-CF2H Cross-coupling：Difluoromethylation of Ketene dithioacetal
The difluoromethylation of various substrates has experienced significant advancements with the rapid development of photo...
TBADT/nickel co-catalyzed arylation of hydrosilanes with aryl halides
Here we report a nickel/photo co-catalyzed direct radical Si-H arylation of hydrosilanes with aryl halides.Tetrabutylammon...
Late-Stage Defluorinative Functionalization: Synthesis of Thioamides and Heterocycles from Trifluoromethylarenes
We report the first general strategy for converting trifluoromethylarenes into thioamides and heterocycles through a teles...
Photocatalytic anti-Markovnikov hydroalkylation of 2-aryl enamides via 1,2-hydrogen atom transfer of amidyl radicals
A novel, efficient and selective photoredox catalytic anti-Markovnikov hydroalkylation of 2-aryl enamides is described. In...
Selective α-Me-C(sp3)-H Borylation of Methyl Sulfides Controlled by Substrate-Ligand Electrostatic Interaction
An iridium/electron-deficient bipyridine-catalyzed selective α-Me-C(sp3)-H borylation of methyl sulfides was disclosed. Th...
Photoinduced direct C-H cyanoalkylation of azauracils via electron donor-acceptor complex activation
Photoinduced C-H functionalization of azauracils predominantly rely on the use of noble metal photocatalysts or synthetica...
Organo-mediator enabled electrochemical 1,4-aryl migration of N-aryl-2-iodobenzamides/N-sulfonyl-2-iodoanilines to access biaryls
Herein, an electroreductive radical 1,4-aryl migration of N-aryl-2-iodobenzamides/N-sulfonyl-2-iodoanilines promoted by ca...
Polymer-Bridged Nanofibrils in a High-Molar-Mass Polyester via Co-assembly of Benzenetricarboxamide End Groups and Additive
Benzenetricarboxamide (BTA) derivatives are versatile compounds widely employed as nucleating agents in commercial semicry...
Reagent-controlled Selective Synthesis of Sulfinamides and Sulfoximines from tert-Butanesulfinamide
The preparation of optically pure sulfinamides from tert-butanesulfinamide previously involved multi-step sequences, inclu...
Cascade cyclization/fluoromethylthiolation of alkynes, unsaturated α‑bromocarbonyls and PhSO2SRF
A copper-catalyzed cyclization/fluoromethylthiolation cascade of alkynes, unsaturated α‑bromocarbonyls and PhSO2SCF2H/PhSO...
Active Electropositive α-Chlorine: Trichloroacetonitrile as an Electrophilic Chlorination Reagent
An inverse-electron C-Cl bond cleavage of Cl3CCN under basic conditions to give chlorine cation was disclosed. The generat...
Brønsted acid enabled metal-free remote oxygenation and amidation of unstrained C–C bonds via 1,4-group migration chaperoned radical-polar crossover
C–C bond functionalization has emerged as a powerful tool for the skeleton editing of organic molecules. However, remote C...
Advances in Photoinduced Radical-Polar Crossover Cyclization (RPCC) of Bifunctional Alkenes
Cyclic architectures refer to a class of molecules that are highly valuable and play significant roles in various well-kno...
Photoinduced Decarbonylative Borylation of Alkyl Aldehyde through 4-Alkyl-1,4-Dihydropyridines
We propose a novel approach for the facile decarbonylative borylation of aliphatic aldehydes. In this strategy, 1,4-dihydr...
Electrocatalytic O-S Bonding Reaction Targeting Biological Macromolecules
This study endeavors to explore the utilization of aromatic sulfinates as bioconjugation handles, addressing the challenge...
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