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Photocatalytic anti-Markovnikov hydroalkylation of 2-aryl enamides via 1,2-hydrogen atom transfer of amidyl radicals
A novel, efficient and selective photoredox catalytic anti-Markovnikov hydroalkylation of 2-aryl enamides is described. In...
Selective α-Me-C(sp3)-H Borylation of Methyl Sulfides Controlled by Substrate-Ligand Electrostatic Interaction
An iridium/electron-deficient bipyridine-catalyzed selective α-Me-C(sp3)-H borylation of methyl sulfides was disclosed. Th...
Photoinduced direct C-H cyanoalkylation of azauracils via electron donor-acceptor complex activation
Photoinduced C-H functionalization of azauracils predominantly rely on the use of noble metal photocatalysts or synthetica...
Organo-mediator enabled electrochemical 1,4-aryl migration of N-aryl-2-iodobenzamides/N-sulfonyl-2-iodoanilines to access biaryls
Herein, an electroreductive radical 1,4-aryl migration of N-aryl-2-iodobenzamides/N-sulfonyl-2-iodoanilines promoted by ca...
Polymer-Bridged Nanofibrils in a High-Molar-Mass Polyester via Co-assembly of Benzenetricarboxamide End Groups and Additive
Benzenetricarboxamide (BTA) derivatives are versatile compounds widely employed as nucleating agents in commercial semicry...
Reagent-controlled Selective Synthesis of Sulfinamides and Sulfoximines from tert-Butanesulfinamide
The preparation of optically pure sulfinamides from tert-butanesulfinamide previously involved multi-step sequences, inclu...
Cascade cyclization/fluoromethylthiolation of alkynes, unsaturated α‑bromocarbonyls and PhSO2SRF
A copper-catalyzed cyclization/fluoromethylthiolation cascade of alkynes, unsaturated α‑bromocarbonyls and PhSO2SCF2H/PhSO...
Active Electropositive α-Chlorine: Trichloroacetonitrile as an Electrophilic Chlorination Reagent
An inverse-electron C-Cl bond cleavage of Cl3CCN under basic conditions to give chlorine cation was disclosed. The generat...
Brønsted acid enabled metal-free remote oxygenation and amidation of unstrained C–C bonds via 1,4-group migration chaperoned radical-polar crossover
C–C bond functionalization has emerged as a powerful tool for the skeleton editing of organic molecules. However, remote C...
Advances in Photoinduced Radical-Polar Crossover Cyclization (RPCC) of Bifunctional Alkenes
Cyclic architectures refer to a class of molecules that are highly valuable and play significant roles in various well-kno...
Photoinduced Decarbonylative Borylation of Alkyl Aldehyde through 4-Alkyl-1,4-Dihydropyridines
We propose a novel approach for the facile decarbonylative borylation of aliphatic aldehydes. In this strategy, 1,4-dihydr...
Electrocatalytic O-S Bonding Reaction Targeting Biological Macromolecules
This study endeavors to explore the utilization of aromatic sulfinates as bioconjugation handles, addressing the challenge...
Enantioselective synthesis of chiral BCPs
Bicyclo[1.1.1]pentanes (BCPs) have emerged as an interesting scaffold in drug design. This strained molecule can act as bi...
Dithiocarbamate mediated thioamidation via C-C single bond cleavage of styrene: Study of the protocol on decarbonylative and decarboxylative thioamidations
Dithiocarbamate salts have been explored in a novel C-C thioamidation of styrene in presence of ammonium persulfate and mo...
Highly regio- and stereoselective bromochlorination and bromoazidation of 1,3-dienes
A substrate-induced strategy for the bromochlorination and bromoazidation of diverse 1,3-dienes has been reported. This pr...
Metal-free photocatalytic homo- and cross dimerization of α-hydroxy ketones via dual C(sp3)-H functionalization: synthesis of 2,3-dihydroxy-1,4-butanediones
The dimerization reactions of α-hydroxy ketones in the α-carbon site have been realized by visible light photocatalysis in...
Electrochemistry multicomponent cascade annulation and functionalization reaction to enable C(sp3)-H trifluoromethylation
Herein, we describe a novel electrochemistry facilitated one-pot multicomponent cascade annulation and bi-functionalizatio...
Gold-catalyzed cyclization/nucleophilic addition reaction of o-alkynylanilines with ynamides: stereoselective synthesis of 3-vinylindoles
The functionalized 3-vinylindoles were obtained through the cyclization/nucleophilic addition of ynamides and o-alkynylani...
Obscurinin A, a unique Lycopodium alkaloid possessing an 8/6/6/6/5 pentacyclic system isolated from Lycopodium obscurum L.
Obscurinin A (1), an unprecedented Lycopodium alkaloid featuring an 8/6/6/6/5 ring system, was isolated from the methanol ...
Palladium-catalyzed [6+4] cycloaddition with π-allyl all-carbon 1,6-dipole for the synthesis of ten-membered heterocycles
This paper presents the design and synthesis of a novel α,α-diester-δ-vinylvalerolactone, utilized as a new all-carbon dip...
Catalyst-free photoarylation reactions promoted by visible light
The use of visible light as a means of promoting chemical transformations offers a more sustainable and efficient alternat...
Experimental and Computational Studies on the Palladium-catalyzed Intramolecular Dearomatization, Electrophilic Addition, Intermolecular Coupling Sequence
An unprecedented Pd-catalyzed highly stereoselective synthetic strategy for the construction of a broad spectrum of polycy...
Recent Advances on Hydrogen Atom Transfer Induced C(sp3)-H Functionalizations Initiated by Radical Addition to Alkynes
Direct functionalization of C(sp3)-H bonds represents a pivotal objective in the realm of synthetic chemistry. However, th...
Distal Iodine Migration of Arylalkynes via Cyclic Monoaryliodonium Salts
Disclosed herein is a novel protocol for the synthesis of cyclic monoaryliodonium salts (CMAIs) from readily available iod...
Nickel-Catalyzed Reductive 1,1-Diarylation of Unactivated Alkenes with Aryl Iodide
In this article, we wish to present a nickel-catalyzed reductive 1,1-diarylation reaction of unactivated alkenes with aryl...
Rapid Synthesis of Benzofulvenes from α-Bromodiarylethylenes Based on a 1,4-Palladium Shift Strategy
A palladium-catalyzed synthesis of benzofulvenes from α-halo diarylethylenes has been reported. The reaction proceeds thro...
Catalyst-free Photoinduced Radical Sulfonylation/Cyclization of Unactivated Alkenes toward Sulfone-containing Quinazolinones
The difunctionalization of alkenes based on the insertion of sulfur dioxide has been considered to be one of the most stra...
An aminobenzannulation reaction of propargylic ester and isocyanide to access multi-functionalized aryl amine derivatives
An aminobenzannulation of two molecular isocyanides and propargylic ester has been reported. This reaction involves sequen...
Self-detachable protecting group function of CO2 in the electrochemical reduction of aryl azides
A unique self-detachable protecting group function of CO2 in the selective electrochemical reduction of azides is discover...
Photoredox Catalyzed Release of Carbon-based Radicals from 2-Substituted-1,3-imidazolidines
In the frame of developing easy oxidizable compounds for the photorelease of carbon-based radicals, we described herein th...
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