MnO nanoparticles supported on g-CN-M for the selective oxidation of cumene to 2-phenyl-2-propanol

GONG Jia-xin, HU Shou-yao, XIONG Yu. Designing catalysts to formic acid oxidation reaction: From nanoscale to single atoms [J]. Journal of Central South University, 2024, 31(12): 4586–4600. DOI: https://doi.org/10.1007/s11771-024-5831-0.

Article  Google Scholar 

ZOUHEIR M, TANJI K, NAVIO J A, et al. Effective photocatalytic conversion of formic acid using iron, copper and sulphate doped TiO2 [J]. Journal of Central South University, 2022, 29(11): 3592–3607. DOI: https://doi.org/10.1007/s11771-022-5172-9.

Article  Google Scholar 

XU Si-quan, PAN Dong-hui, XIAO Guo-min. Enhanced HMF yield from glucose with H-ZSM-5 catalyst in water - tetrahydrofuran/2-butanol/2-methyltetrahydrofuran biphasic systems [J]. Journal of Central South University, 2019, 26(11): 2974–2986. DOI: https://doi.org/10.1007/s11771-019-4229-x.

Article  Google Scholar 

DENG Yu-chan, CHEN Zhi-cheng, HUANG Jiang-nan, et al. MnO2 nanoparticles supported on CNTs for cumene oxidation: Synergistic effect and kinetic modelling [J]. Chemical Engineering Journal, 2022, 444: 136666. DOI: https://doi.org/10.1016/j.cej.2022.136666.

Article  Google Scholar 

LUO Zhi-shan, WAN Qiang, YU Zhi-yang, et al. Photofluorination of nanodiamonds catalyzing oxidative dehydrogenation reaction of ethylbenzene [J]. Nature Communications, 2021, 12: 6542. DOI: https://doi.org/10.1038/s41467-021-26891-8.

Article  Google Scholar 

MONTJOY D G, WILSON E A K, HOU H, et al. Photocatalytic cyclohexane oxidation and epoxidation using hedgehog particles [J]. Nature Communications, 2023, 14: 857. DOI: https://doi.org/10.1038/s41467-023-36473-5.

Article  Google Scholar 

VOMERI A, STUCCHI M, VILLA A, et al. New insights for the catalytic oxidation of cyclohexane to K-a oil [J]. Journal of Energy Chemistry, 2022, 70: 45–51. DOI: https://doi.org/10.1016/j.jechem.2022.02.008.

Article  Google Scholar 

DING Li-hong, SUN Xiu-liang, HUANG Chong-pin, et al. Insights into the mechanism of cumene catalytic oxidation using ionic liquid [Bmim] OH [J]. Molecular Catalysis, 2023, 538: 113008. DOI: https://doi.org/10.1016/j.mcat.2023.113008.

Article  Google Scholar 

NAVARRO-GARCÍA Á, GÓMEZ M, MURCIA M D, et al. Photodegradation of polyethylene terephthalate and bis(2-hydroxyethyl) terephthalate using excimer lamps and hydrogen peroxide: A strategy for PET - derived waste treatment [J]. Molecules, 2025, 30(15): 3302. DOI: https://doi.org/10.3390/molecules30153302.

Article  Google Scholar 

DONG Peng, SHAO Ting-na, LI Jin-lian, et al. The tandem catalysis of porous CoW composite oxide: Intensified allylic oxidation of cyclohexene to 2-cyclohexene-1-one [J]. Molecular Catalysis, 2024, 556: 113955. DOI: https://doi.org/10.1016/j.mcat.2024.113955.

Article  Google Scholar 

HU Dong-ming, WANG Wan-jing, ZHANG Tian, et al. Achieving high yield production of p-methylbenzaldehyde from p-methylstyrene oxidation over Co-doped CeO2 microshuttles [J]. Research on Chemical Intermediates, 2025, 51(3): 1329–1339. DOI: https://doi.org/10.1007/s11164-025-05512-9.

Article  Google Scholar 

ZHANG Yi-cheng, WU Si-yu, MA Yue-tong, et al. Application, characterization, and simulation of CuO-ZnO-TiO2 for catalytic oxidation of cumene to cumene hydroperoxide [J]. Industrial & Engineering Chemistry Research, 2025, 64(15): 7670–7678.

Article  Google Scholar 

HAO Shu-hong, HE Jie-ting, TANG Qiong, et al. Constructing highly dispersed Pd on Ca-Al layered double hydroxide for efficiently selective oxidation of cumene [J]. Molecular Catalysis, 2024, 568: 114490. DOI: https://doi.org/10.1016/j.mcat.2024.114490.

Article  Google Scholar 

CONLEY M L, MOHAMMED F S, WINSLOW C, et al. Mechanism of acid-catalyzed decomposition of dicumyl peroxide in dodecane: Intermediacy of cumene hydroperoxide [J]. Industrial & Engineering Chemistry Research, 2016, 55(20): 5865–5873.

Article  Google Scholar 

DUGHERI S, FANFANI N, CAPPELLI G, et al. Regarding bioanalysis lasting a few minutes: Automated cooling-SPME and fast-GC for urinary 2-phenyl-2-propanol monitoring [J]. Toxics, 2024, 12(10): 743. DOI: https://doi.org/10.3390/toxics12100743.

Article  Google Scholar 

WANG Shun-yao, FENG Gui, LV Han, et al. Hazard assessment of thermal decomposition behavior of cumene hydroperoxide under heterogeneous temperature system [J]. Case Studies in Thermal Engineering, 2024, 53: 103860. DOI: https://doi.org/10.1016/j.csite.2023.103860.

Article  Google Scholar 

BHADANGE S A, PATIL N T. Gold redox catalysis with hydrogen peroxide [J]. Nature Chemistry, 2025, 17(6): 784–785. DOI: https://doi.org/10.1038/s41557-025-01838-4.

Article  Google Scholar 

PEREGO C. Kinetics of the cumyl hydroperoxide acid cleavage: A case study [J]. Chemie Ingenieur Technik, 2025, 97(10): 974–985. DOI: https://doi.org/10.1002/cite.70008.

Article  Google Scholar 

ZHOU Jin-wen, SUN Xiu-liang, HUANG Chong-pin, et al. Experimental and theoretical study on ionic liquid [Bmim] Br-catalyzed decomposition of cumene hydroperoxide into dimethylbenzyl alcohol [J]. Applied Catalysis A: General, 2023, 656: 119116. DOI: https://doi.org/10.1016/j.apcata.2023.119116.

Article  Google Scholar 

WAN Chao, LI Rong, WANG Jia-pei, et al. Silica confinement for stable and magnetic Co - Cu alloy nanoparticles in nitrogen-doped carbon for enhanced hydrogen evolution [J]. Angewandte Chemie International Edition, 2024, 63(24): e202404505. DOI: https://doi.org/10.1002/anie.202404505.

Article  Google Scholar 

ZHANG Yu-bo, WANG Pan, YU Dan, et al. Evolution mechanism of active sites for selective catalytic reduction of NOx with NH3 over Fe-ZSM-5 catalysts doped by Ce/Cu [J]. Journal of Central South University, 2022, 29(7): 2239–2252. DOI: https://doi.org/10.1007/s11771-022-5077-7.

Article  Google Scholar 

WAN Chao, ZHOU Liu, XU Shu-man, et al. Defect engineered mesoporous graphitic carbon nitride modified with AgPd nanoparticles for enhanced photocatalytic hydrogen evolution from formic acid [J]. Chemical Engineering Journal, 2022, 429: 132388. DOI: https://doi.org/10.1016/j.cej.2021.132388.

Article  Google Scholar 

WAN Chao, LI Gui, WANG Jia-pei, et al. Modulating electronic metal-support interactions to boost visible-light-driven hydrolysis of ammonia borane: Nickel-platinum nanoparticles supported on phosphorus-doped titania [J]. Angewandte Chemie International Edition, 2023, 62(40): e202305371. DOI: https://doi.org/10.1002/anie.202305371.

Article  Google Scholar 

REN Wen-ting, LIU Shu-yu, WANG Yan, et al. Sea urchinlike NiPt/TiCeO2 catalyst for rapid and efficient hydrogen production from hydrous hydrazine [J]. Journal of Rare Earths, 2025, 43(8): 1668–1676. DOI: https://doi.org/10.1016/j.jre.2025.03.007.

Article  Google Scholar 

LIU Shu-yu, REN Wen-ting, CHEN Lei-yun, et al. Constructing urchin-like TiO2 integrated NiPt nanoparticles for boosting the decomposition of hydrazine hydrate [J]. Rare Metals, 2025, 44(9): 6331–6342. DOI: https://doi.org/10.1007/s12598-025-03378-9.

Article  Google Scholar 

WAN Chao, LIU Xiao-ling, WANG Jia-pei, et al. Heterostructuring 2D Co2P nanosheets with 0D CoP via a salt-assisted strategy for boosting hydrogen evolution from ammonia borane hydrolysis [J]. Nano Research, 2023, 16(5): 6260–6269. DOI: https://doi.org/10.1007/s12274-023-5388-5.

Article  Google Scholar 

WAN Chao, LIANG Yu, ZHOU Liu, et al. Integration of morphology and electronic structure modulation on cobalt phosphide nanosheets to boost photocatalytic hydrogen evolution from ammonia borane hydrolysis [J]. Green Energy & Environment, 2024, 9(2): 333–343. DOI: https://doi.org/10.1016/j.gee.2022.06.007.

Article  Google Scholar 

YANG Wen-hao, SU Zi-ang, XU Zheng-hao, et al. Comparative study of α -, β -, γ - and δ-MnO2 on toluene oxidation: Oxygen vacancies and reaction intermediates [J]. Applied Catalysis B: Environmental, 2020, 260: 118150. DOI: https://doi.org/10.1016/j.apcatb.2019.118150.

Article  Google Scholar 

LIU Li-zhong, LI Jue-xue, ZHANG Hong-bo, et al. In situ fabrication of highly active y -MnO2/SmMnO3 catalyst for deep catalytic oxidation of gaseous benzene, ethylbenzene, toluene, and o-xylene [J]. Journal of Hazardous Materials, 2019, 362: 178–186. DOI: https://doi.org/10.1016/j.jhazmat.2018.09.012.

Article  Google Scholar 

KE Qing-ping, ZHANG Yu-rong, WAN Chao, et al. Sunlight-driven and gram-scale vanillin production via Mn-defected γ-MnO2 catalyst in aqueous environment [J]. Chemical Science, 2024, 15(14): 5368–5375. DOI: https://doi.org/10.1039/d3sc05654f.

Article  Google Scholar 

MO Sheng-peng, ZHANG Qi, ZHANG Ming-yuan, et al. Elucidating the special role of strong metal - support interactions in Pt/MnO2 catalysts for total toluene oxidation [J]. Nanoscale Horizons, 2019, 4(6): 1425–1433.

Article  Google Scholar 

LI Lu-ming, LUO Jing-jie, LIU Yue-feng, et al. Self-propagated flaming synthesis of highly active layered CuO-S -MnO2 hybrid composites for catalytic total oxidation of toluene pollutant [J]. ACS Applied Materials & Interfaces, 2017, 9(26): 21798–21808.

Article  Google Scholar 

QIN Yuan, WANG Yi, LI Jia-min, et al. Effect of Ag on toluene oxidation over Ag supported wire-like MnO2 catalysts [J]. Surfaces and Interfaces, 2020, 21: 100657. DOI: https://doi.org/10.1016/j.surfin.2020.100657.

Article  Google Scholar 

MU Chun-lin, CAO Yong-hai, WANG Hong-juan, et al. A kinetics study on cumene oxidation catalyzed by carbon nanotubes: Effect of N-doping [J]. Chemical Engineering Science, 2018, 177: 391–398. DOI: https://doi.org/10.1016/j.ces.2017.11.016.

Article  Google Scholar 

WANG Li-ping, XIAO Jin, MAO Qiu-yun, et al. Biomass-derived N-doped porous carbon supported single Fe atoms as low-cost and high-performance electrocatalysts for oxygen reduction reaction [J]. Journal of Central South University, 2025, 32(4): 1368–1383. DOI: https://doi.org/10.1007/s11771-025-5954-y.

Article  Google Scholar 

SUN Qi-feng, OU Chang-rui, LIAO Ya-lin, et al. Relationship between pore structure of N-doped 3D porous graphene and electrocatalytic performance of oxygen reduction in zinc-air battery [J]. Journal of Central South University, 2023, 30(5): 1490–1511. DOI: https://doi.org/10.1007/s11771-023-5334-4.

Article  Google Scholar 

DENG Jie, LI Yu-hang, CAO Yong-hai, et al. Trace amounts of Cu(OAc)2 boost the efficiency of cumene oxidation catalyzed by carbon nanotubes washed with HCl [J]. Catalysis Science & Technology, 2020, 10(8): 2523–2530.

Article  Google Scholar 

CHEN Zhi-cheng, LI Yu-hang, CAO Yong-hai, et al. Inhibitory effect of Zn2+ on the chain-initiation process of cumene oxidation [J]. International Journal of Quantum Chemistry, 2021, 121(21): e26780. DOI:

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