Asyraf, M. R. M. et al. in Advanced Composites in Aerospace Engineering Applications (eds Mazlan, N. et al.) 471–498 (Springer, 2022).

Liu, Y. et al. Biomimetic electroactive materials and devices for regenerative engineering. Nat. Rev. Electr. Eng. 2, 188–204 (2025).

Article  Google Scholar 

Naguib, M., Mochalin, V. N., Barsoum, M. W. & Gogotsi, Y. 25th anniversary article: MXenes: a new family of two-dimensional materials. Adv. Mater. 26, 992–1005 (2014).

Article  CAS  PubMed  Google Scholar 

Naguib, M. et al. Two-dimensional nanocrystals produced by exfoliation of Ti3AlC2. Adv. Mater. 23, 4248–4253 (2011).

Article  CAS  PubMed  Google Scholar 

Lipatov, A. et al. High electrical conductivity and breakdown current density of individual monolayer Ti3C2Tx MXene flakes. Matter 4, 1413–1427 (2021).

Article  CAS  Google Scholar 

Lipatov, A. et al. Elastic properties of 2D Ti3C2Tx MXene monolayers and bilayers. Sci. Adv. 4, eaat0491 (2018).

Article  PubMed  PubMed Central  Google Scholar 

Li, X. et al. MXene chemistry, electrochemistry and energy storage applications. Nat. Rev. Chem. 6, 389–404 (2022).

Article  PubMed  Google Scholar 

Gogotsi, Y. & Huang, Q. MXenes: two-dimensional building blocks for future materials and devices. ACS Nano 15, 5775–5780 (2021).

Article  CAS  PubMed  Google Scholar 

Anasori, B., Lukatskaya, M. R. & Gogotsi, Y. 2D metal carbides and nitrides (MXenes) for energy storage. Nat. Rev. Mater. 2, 16098 (2017).

Article  CAS  Google Scholar 

Simon, P. & Gogotsi, Y. Perspectives for electrochemical capacitors and related devices. Nat. Mater. 19, 1151–1163 (2020).

Article  CAS  PubMed  Google Scholar 

Ding, L. et al. MXene molecular sieving membranes for highly efficient gas separation. Nat. Commun. 9, 155 (2018).

Article  PubMed  PubMed Central  Google Scholar 

VahidMohammadi, A., Rosen, J. & Gogotsi, Y. The world of two-dimensional carbides and nitrides (MXenes). Science 372, eabf1581 (2021).

Article  CAS  PubMed  Google Scholar 

Shahzad, F. et al. Electromagnetic interference shielding with 2D transition metal carbides (MXenes). Science 353, 1137–1140 (2016).

Article  CAS  PubMed  Google Scholar 

Iqbal, A. et al. Anomalous absorption of electromagnetic waves by 2D transition metal carbonitride Ti3CNTx (MXene). Science 369, 446–450 (2020).

Article  CAS  PubMed  Google Scholar 

Han, M. et al. Electrochemically modulated interaction of MXenes with microwaves. Nat. Nanotechnol. 18, 373–379 (2023).

Article  CAS  PubMed  Google Scholar 

Yang, M. & Kotov, N. A. Quantitative biomimetics of high-performance materials. Nat. Rev. Mater. 10, 382–395 (2025).

Article  CAS  Google Scholar 

Wegst, U. G. K., Bai, H., Saiz, E., Tomsia, A. P. & Ritchie, R. O. Bioinspired structural materials. Nat. Mater. 14, 23–36 (2015).

Article  CAS  PubMed  Google Scholar 

Barthelat, F., Yin, Z. & Buehler, M. J. Structure and mechanics of interfaces in biological materials. Nat. Rev. Mater. 1, 16007 (2016).

Article  CAS  Google Scholar 

Anasori, B. & Gogotsi, Y. 2D Metal Carbides and Nitrides (MXenes): Structure, Properties and Applications (Springer, 2019).

Xu, B. & Gogotsi, Y. MXenes — the fastest growing materials family in the two-dimensional world. Chin. Chem. Lett. 31, 919–921 (2020).

Article  CAS  Google Scholar 

Gogotsi, Y. & Anasori, B. The rise of MXenes. ACS Nano 13, 8491–8494 (2019).

Article  CAS  PubMed  Google Scholar 

Lim, K. R. G. et al. Fundamentals of MXene synthesis. Nat. Synth. 1, 601–614 (2022).

Article  CAS  Google Scholar 

Alhabeb, M. et al. Guidelines for synthesis and processing of two-dimensional titanium carbide (Ti3C2Tx MXene). Chem. Mater. 29, 7633–7644 (2017).

Article  CAS  Google Scholar 

Sun, Z., Music, D., Ahuja, R., Li, S. & Schneider, J. M. Bonding and classification of nanolayered ternary carbides. Phys. Rev. B 70, 092102 (2004).

Article  Google Scholar 

Barsoum, M. W. MAX Phases: Properties of Machinable Ternary Carbides and Nitrides (Wiley, 2013).

Ghidiu, M., Lukatskaya, M. R., Zhao, M.-Q., Gogotsi, Y. & Barsoum, M. W. Conductive two-dimensional titanium carbide ‘clay’ with high volumetric capacitance. Nature 516, 78–81 (2014).

Article  CAS  PubMed  Google Scholar 

Li, M. et al. Element replacement approach by reaction with Lewis acidic molten salts to synthesize nanolaminated MAX phases and MXenes. J. Am. Chem. Soc. 141, 4730–4737 (2019).

Article  CAS  PubMed  Google Scholar 

Sun, W. et al. Electrochemical etching of Ti2AlC to Ti2CTx (MXene) in low-concentration hydrochloric acid solution. J. Mater. Chem. A 5, 21663–21668 (2017).

Article  CAS  Google Scholar 

Yang, S. et al. Fluoride-free synthesis of two-dimensional titanium carbide (MXene) using a binary aqueous system. Angew. Chem. Int. Ed. 130, 15717–15721 (2018).

Article  Google Scholar 

Naguib, M. et al. New two-dimensional niobium and vanadium carbides as promising materials for Li-ion batteries. J. Am. Chem. Soc. 135, 15966–15969 (2013).

Article  CAS  PubMed  Google Scholar 

Anasori, B. et al. Two-dimensional, ordered, double transition metals carbides (MXenes). ACS Nano 9, 9507–9516 (2015).

Article  CAS  PubMed  Google Scholar 

Naguib, M. et al. Two-dimensional transition metal carbides. ACS Nano 6, 1322–1331 (2012).

Article  CAS  PubMed  Google Scholar 

Wei, Y., Zhang, P., Soomro, R. A., Zhu, Q. & Xu, B. Advances in the synthesis of 2D MXenes. Adv. Mater. 33, 2103148 (2021).

Article  CAS  Google Scholar 

Sang, X. et al. Atomic defects in monolayer titanium carbide (Ti3C2Tx) MXene. ACS Nano 10, 9193–9200 (2016).

Article  CAS  PubMed  Google Scholar 

Li, Y. et al. A general Lewis acidic etching route for preparing MXenes with enhanced electrochemical performance in non-aqueous electrolyte. Nat. Mater. 19, 894–899 (2020).

Article  CAS  PubMed  Google Scholar 

Urbankowski, P. et al. Synthesis of two-dimensional titanium nitride Ti4N3 (MXene). Nanoscale 8, 11385–11391 (2016).

Article  CAS  PubMed  Google Scholar 

Kamysbayev, V. et al. Covalent surface modifications and superconductivity of two-dimensional metal carbide MXenes. Science 369, 979–983 (2020).

Article  CAS  PubMed  Google Scholar 

Liu, L. et al. Exfoliation and delamination of Ti3C2Tx MXene prepared via molten salt etching route. ACS Nano 16, 111–118 (2022).

Article  CAS  PubMed