Hill, N. A. Why are there so few magnetic ferroelectrics? J. Phys. Chem. B 104, 6694–6709 (2000).
Landau, L. D. & Lifshitz, E. M. Electrodynamics of Continuous Media (Pergamon Press, 1956).
Dzyaloshinskii, I. E. On the magneto-electrical effect in antiferromagnets. Sov. Phys. JETP 10, 628–629 (1960).
Astrov, D. N. The magnetoelectric effect in antiferromagnetics. Sov. Phys. JETP 11, 708–709 (1960).
Mercier, M., Gareyte, J. & Bertaut, E. F. Une Nouvelle Famille De Corps Magnetoelectriques - LiMPO4 (M=Mn,Co,Ni). C. R. Acad. Sci. B 264, 979 (1967).
Ascher, E., Rieder, H., Schmid, H. & Stössel, H. Some properties of ferromagnetoelectric nickel-iodine boracite, Ni3B7O13I. J. Appl. Phys. 37, 1404–1405 (1966).
Bertaut, F., Forrat, F. & Fang, P. Les manganites de terres rares et d’yttrium: une nouvelle classe de ferroélectriques. C. R., Acad. Sci. 246, 1958 (1963).
Smolenskii, G. A. & Bokov, V. A. Coexistence of magnetic and electric ordering in crystals. J. Appl. Phys. 35, 915–918 (1964).
Schmid, H. On a magnetoelectric classification of materials. Int. J. Magnetism 4, 337–361 (1973).
Teague, J. R., Gerson, R. & James, W. J. Dielectric hysteresis in single crystal BiFeO3. Solid State Commun. 8, 1073–1074 (1970).
Pearson, R. G. The second-order Jahn–Teller effect. J. Molec. Struc. 103, 25–34 (1983).
Burdett, J. K. Use of the Jahn–Teller theorem in inorganic chemistry. Inorg. Chem. 20, 1959–1962 (1981).
Nan, C.-W., Bichurin, M. I., Dong, S., Viehland, D. & Srinivasan, G. Multiferroic magnetoelectric composites: historical perspective, status, and future directions. J. Appl. Phys. 103, 031101 (2008).
Gradauskaite, E., Meisenheimer, P., Müller, M., Heron, J. & Trassin, M. Multiferroic heterostructures for spintronics. Phys. Sci. Rev. 6, 20190072 (2020).
Baltz, V. et al. Antiferromagnetic spintronics. Rev. Mod. Phys. 90, 015005 (2018).
Marthinsen, A., Faber, C., Aschauer, U., Spaldin, N. A. & Selbach, S. M. Coupling and competition between ferroelectricity, magnetism, strain, and oxygen vacancies in AMnO3 perovskites. MRS Commun. 6, 182–191 (2016).
Ederer, C. & Spaldin, N. A. Origin of ferroelectricity in the multiferroic barium fluorides BaMF4. Phys. Rev. B 74, 024102 (2006).
van Aken, B. B., Palstra, T. T. M., Filippetti, A. & Spaldin, N. A. The origin of ferroelectricity in magnetoelectric YMnO3. Nat. Mater. 3, 164–170 (2004).
Fennie, C. J. & Rabe, K. M. Ferroelectric transition in YMnO3 from first principles. Phys. Rev. B 72, 100103(R) (2005).
Benedek, N. A. & Fennie, C. J. Hybrid improper ferroelectricity: a mechanism for controllable polarization-magnetization coupling. Phys. Rev. Lett. 106, 107204 (2011).
Wang, J. et al. Epitaxial BiFeO3 multiferroic thin film heterostructures. Science 299, 1719–1722 (2003).
Article CAS PubMed Google Scholar
Hill, N. A. & Rabe, K. M. First principles investigation of ferromagnetism and ferroelectricity in BiMnO3. Phys. Rev. B 59, 8759–8769 (1999).
Chiba, H., Atou, T. & Syono, Y. Magnetic and electrical properties of Bi1−xSrxMnO3: hole-doping effect on ferromagnetic perovskite BiMnO3. J. Solid State Chem. 132, 139–143 (1997).
dos Santos, A. M. et al. Orbital ordering as the determinant for ferromagnetism in biferroic BiMnO3. Phys. Rev. B 66, 064425 (2002).
Baettig, P., Seshadri, R. & Spaldin, N. A. Anti-polarity in ideal BiMnO3. J. Am. Chem. Soc. 129, 9854–9855 (2007).
Article CAS PubMed Google Scholar
Belik, A. A. et al. Origin of the monoclinic-to-monoclinic phase transition and evidence for the centrosymmetric crystal structure of BiMnO3. J. Am. Chem. Soc. 129, 971–977 (2007).
Article CAS PubMed Google Scholar
Goodenough, J. B. & Zhou, J. Varied roles of Pb in transition-metal PbMO3 perovskites (M = Ti, V, Cr, Mn, Fe, Ni, Ru). Sci. Technol. Adv. Mater. 16, 036003 (2016).
Rushchanskii, K. et al. A multiferroic material to search for the permanent electric dipole moment of the electron. Nat. Mater. 9, 649–654 (2010).
Article CAS PubMed Google Scholar
Lee, J. H. et al. A strong ferroelectric ferromagnet created by means of spin-lattice coupling. Nature 466, 954–959 (2010).
Article CAS PubMed Google Scholar
Narayan, A., Cano, A., Balatsky, A. V. & Spaldin, N. A. Multiferroic quantum criticality. Nat. Mater. 18, 223–228 (2019).
Article CAS PubMed Google Scholar
Bhattacharjee, S., Bousquet, E. & Ghosez, P. Engineering multiferroism in CaMnO3. Phys. Rev. Lett. 102, 117602 (2009).
Günter, T. et al. Incipient ferroelectricity in 2.3% tensile-strained CaMnO3 films. Phys. Rev. B 85, 214120 (2012).
Rondinelli, J. M., Eidelson, A. S. & Spaldin, N. A. Non-d0 Mn-driven ferroelectricity in antiferromagnetic BaMnO3. Phys. Rev. B 79, 205119 (2009).
Sakai, H. et al. Displacement-type ferroelectricity with off-center magnetic ions in perovskite Sr1−xBaxMnO3. Phys. Rev. Lett. 107, 137601 (2011).
Article CAS PubMed Google Scholar
Goian, V. et al. Making EuO multiferroic by epitaxial strain engineering. Commun. Mater. 74, 1–10 (2020).
Mundy, J. A. et al. Liberating a hidden antiferroelectric phase with interfacial electrostatic engineering. Sci. Adv. 8, eabg5860 (2022).
Article CAS PubMed PubMed Central Google Scholar
Gattinoni, C. & Spaldin, N. A. Prediction of a strong polarizing field in thin film paraelectrics. Phys. Rev. Res. 4, L032020 (2022).
Picozzi, S., Yamauchi, K., Sanyal, B., Sergienko, I. A. & Dagotto, E. Dual nature of improper ferroelectricity in a magnetoelectric multiferroic. Phys. Rev. Lett. 99, 227201 (2007).
Article CAS PubMed Google Scholar
Okuyama, D. et al. Magnetically driven ferroelectric atomic displacements in orthorhombic YMnO3. Phys. Rev. B 84, 054440 (2011).
Kimura, T. et al. Magnetic control of ferroelectric polarization. Nature 426, 55–58 (2003).
Article CAS PubMed Google Scholar
Mostovoy, M. Ferroelectricity in spiral magnets. Phys. Rev. Lett. 96, 067601 (2006).
Morin, M. et al. Tuning magnetic spirals beyond room temperature with chemical disorder. Nat. Commun. 7, 13758 (2016).
Comments (0)