Wang, Y. et al. Mimicking natural photosynthesis: solar to renewable H2 fuel synthesis by Z-scheme water splitting systems. Chem. Rev. 118, 5201–5241 (2018).
Article CAS PubMed PubMed Central Google Scholar
Nishiyama, H. et al. Photocatalytic solar hydrogen production from water on a 100-m2 scale. Nature 598, 304–307 (2021).
Article CAS PubMed Google Scholar
Wang, Q. & Domen, K. Particulate photocatalysts for light-driven water splitting: mechanisms, challenges, and design strategies. Chem. Rev. 120, 919–985 (2020).
Article CAS PubMed Google Scholar
Kudo, A. & Miseki, Y. Heterogeneous photocatalyst materials for water splitting. Chem. Soc. Rev. 38, 253–278 (2009).
Article CAS PubMed Google Scholar
Lin, L. et al. Molecular-level insights on the reactive facet of carbon nitride single crystals photocatalysing overall water splitting. Nat. Catal. 3, 649–655 (2020).
Mu, L. et al. Enhancing charge separation on high symmetry SrTiO3 exposed with anisotropic facets for photocatalytic water splitting. Energy Environ. Sci. 9, 2463–2469 (2016).
Sato, J., Kobayashi, H. & Inoue, Y. Photocatalytic activity for water decomposition of indates with octahedrally coordinated d10 configuration. II. Roles of geometric and electronic structures. J. Phys. Chem. B 107, 7970–7975 (2003).
Wang, Q. et al. Bottom-up synthesis of single-crystalline poly (triazine imide) nanosheets for photocatalytic overall water splitting. Angew. Chem. Int. Ed. 62, e202307930 (2023).
Takata, T. et al. Photocatalytic water splitting with a quantum efficiency of almost unity. Nature 581, 411–414 (2020).
Article CAS PubMed Google Scholar
Li, Z. et al. Blocking the reverse reactions of overall water splitting on a Rh/GaN–ZnO photocatalyst modified with Al2O3. Nat. Catal. 6, 80–88 (2023).
Wang, Q. et al. Scalable water splitting on particulate photocatalyst sheets with a solar-to-hydrogen energy conversion efficiency exceeding 1%. Nat. Mater. 15, 611–615 (2016).
Article CAS PubMed Google Scholar
Lyu, H. et al. An Al-doped SrTiO3 photocatalyst maintaining sunlight-driven overall water splitting activity for over 1000 h of constant illumination. Chem. Sci. 10, 3196–3201 (2019).
Article CAS PubMed PubMed Central Google Scholar
Domen, K., Kudo, A. & Onishi, T. Mechanism of photocatalytic decomposition of water into H2 and O2 over NiO–SrTiO3. J. Catal. 102, 92–98 (1986).
Maeda, K. et al. GaN:ZnO solid solution as a photocatalyst for visible-light-driven overall water splitting. J. Am. Chem. Soc. 127, 8286–8287 (2005).
Article CAS PubMed Google Scholar
Townsend, T. K., Browning, N. D. & Osterloh, F. E. Overall photocatalytic water splitting with NiOx-SrTiO3—a revised mechanism. Energy Environ. Sci. 5, 9543–9550 (2012).
Maeda, K. et al. Preparation of core–shell-structured nanoparticles (with a noble-metal or metal oxide core and a chromia shell) and their application in water splitting by means of visible light. Chem. Eur. J. 16, 7750–7759 (2010).
Article CAS PubMed Google Scholar
Sakamoto, R. et al. Coordination chemistry for innovative carbon-related materials. Coord. Chem. Rev. 466, 214577 (2022).
Feng, D. et al. Robust and conductive two-dimensional metal–organic frameworks with exceptionally high volumetric and areal capacitance. Nat. Energy 3, 30–36 (2018).
Sheberla, D. et al. Conductive MOF electrodes for stable supercapacitors with high areal capacitance. Nat. Mater. 16, 220–224 (2017).
Article CAS PubMed Google Scholar
Smith, M. K. & Mirica, K. A. Self-organized frameworks on textiles (SOFT): conductive fabrics for simultaneous sensing, capture, and filtration of gases. J. Am. Chem. Soc. 139, 16759–16767 (2017).
Article CAS PubMed Google Scholar
Toyoda, R. et al. Heterometallic benzenehexathiolato coordination nanosheets: periodic structure improves crystallinity and electrical conductivity. Adv. Mater. 34, 2106204 (2022).
Huang, X. et al. A two-dimensional π–d conjugated coordination polymer with extremely high electrical conductivity and ambipolar transport behaviour. Nat. Commun. 6, 7408 (2015).
Article CAS PubMed PubMed Central Google Scholar
Yuan, S. et al. Tunable metal hydroxide–organic frameworks for catalysing oxygen evolution. Nat. Mater. 21, 673–680 (2022).
Article CAS PubMed Google Scholar
Geng, B. et al. Conductive CuCo-based bimetal organic framework for efficient hydrogen evolution. Adv. Mater. 33, 2106781 (2021).
Miner, E. M. et al. Electrochemical oxygen reduction catalysed by Ni3(hexaiminotriphenylene)2. Nat. Commun. 7, 10942 (2016).
Article CAS PubMed PubMed Central Google Scholar
Guan, J. et al. Two-dimensional metal–organic framework acts as a hydrogen evolution cocatalyst for overall photocatalytic water splitting. ACS Catal. 12, 3881–3889 (2022).
Guan, J. et al. Manipulating the morphology and electronic state of a two-dimensional coordination polymer as a hydrogen evolution cocatalyst enhances photocatalytic overall water splitting. ACS Catal. 14, 1146–1156 (2024).
Hmadeh, M. et al. New porous crystals of extended metal-catecholates. Chem. Mater. 24, 3511–3513 (2012).
Rubio-Giménez, V. et al. Bottom-up fabrication of semiconductive metal–organic framework ultrathin films. Adv. Mater. 30, 1704291 (2018).
Snook, K. M., Zasada, L. B., Chehada, D. & Xiao, D. J. Oxidative control over the morphology of Cu3(HHTP)2, a 2D conductive metal–organic framework. Chem. Sci. 13, 10472–10478 (2022).
Article CAS PubMed PubMed Central Google Scholar
Day, R. W. et al. Single crystals of electrically conductive two-dimensional metal–organic frameworks: structural and electrical transport properties. ACS Cent. Sci. 5, 1959–1964 (2019).
Article CAS PubMed PubMed Central Google Scholar
Wrogemann, J. M. et al. Overcoming diffusion limitation of Faradaic processes: property-performance relationships of 2D conductive metal–organic framework Cu3(HHTP)2 for reversible lithium-ion storage. Angew. Chem. Int. Ed. 62, e202303111 (2023).
Eagleton, A. M., Ambrogi, E. K., Miller, S. A., Vereshchuk, N. & Mirica, K. A. Fiber integrated metal–organic frameworks as functional components in smart textiles. Angew. Chem. Int. Ed. 62, e202309078 (2023).
Xiao, J. et al. Sub-50 nm perovskite-type tantalum-based oxynitride single crystals with enhanced photoactivity for water splitting. Nat. Commun. 14, 8030 (2023).
Comments (0)